Investigate the production, in a school laboratory, of simple esters

[cs_content][cs_section parallax=”false” separator_top_type=”none” separator_top_height=”50px” separator_top_angle_point=”50″ separator_bottom_type=”none” separator_bottom_height=”50px” separator_bottom_angle_point=”50″ style=”margin: 0px;padding: 45px 0px;”][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”][cs_text]Organic Chemistry > Reactions of Organic Acids and Bases >[/cs_text][cs_text]Preparation of simple esters

Required Reagents:

  • sulphuric acid
  • A range of alcohols
  • A range of carboxylic acids
  • 3 x boiling tubes
  • Large beaker to act as a water bath
  • 250cm3
  • Beaker with the cold water
  • 0-100 °C thermometer
  • 10cm3
  • Measuring cylinder
  • Stirring rod
  • Spatula
  • Access to kettle
  • Mass balance
  • Dropping pipette

Procedure:

  1. Place 1cm3 of methanol and 3g of salicylic acid in a boiling tube. Mix well and carefully add a few drops of conc. sulphuric acid.
  2. Place the boiling tube in a water bath at about 80°C for five minutes.
  3. Pour the contents of the boiling tube into a beaker of cold water.
  4. Carefully smell the ester floating on the water.
  5. Place 1cm3 of ethanol and 1cm3 of ethanoic acid in a boiling tube. Mix well and carefully add a few drops of conc. sulphuric acid.
  6. Repeat steps 2 – 4.
  7. Try other alcohol/carboxylic acid combinations.

Result:

A fruity smell will be observed indicating the presence of esters. Further identification tests can be conducted for confirmation.[/cs_text][/cs_column][/cs_row][/cs_section][/cs_content]

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