Esterification and Catalysis

[cs_content][cs_section parallax=”false” separator_top_type=”none” separator_top_height=”50px” separator_top_angle_point=”50″ separator_bottom_type=”none” separator_bottom_height=”50px” separator_bottom_angle_point=”50″ style=”margin: 0px;padding: 45px 0px;”][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”][cs_text]The Acidic Environment‎ > ‎5. Esterification‎ > ‎

Describe the purpose of using acid in esterification for catalysis[/cs_text][/cs_column][/cs_row][/cs_section][cs_section parallax=”false” separator_top_type=”none” separator_top_height=”50px” separator_top_angle_point=”50″ separator_bottom_type=”none” separator_bottom_height=”50px” separator_bottom_angle_point=”50″ style=”margin: 0px;padding: 45px 0px;”][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”][cs_text]

  • Esterification is a relatively slow process at room temperature and does not proceed to completion.
  • Concentrated sulfuric acid is used as a catalyst, and has a dual role:
    • Speeds up the reaction.
    • Acts as a dehydrating agent, forcing the equilibrium to the right and resulting in a greater yield of ester.
  • Only very small amounts of sulfuric acid are used, as large amounts would be wasteful, uneconomical, and would complicate the final separation processes.
  • Therefore, the addition of the acid does not have a considerable impact on the yield of ester.
  • In addition to the catalyst, esterification reactions are usually carried out at temperatures near the boiling point of the alcohol being reacted, which also increases the reaction rate.

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