Deduce the equilibrium expression (in terms of Keq) for homogeneous reactions occurring in solution

[cs_content][cs_section parallax=”false” separator_top_type=”none” separator_top_height=”50px” separator_top_angle_point=”50″ separator_bottom_type=”none” separator_bottom_height=”50px” separator_bottom_angle_point=”50″ style=”margin: 0px;padding: 45px 0px;”][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”][cs_text]Equilibrium and Acid Reactions > Calculating the Equilibrium Constant (Keq) >[/cs_text][cs_text]A homogeneous equilibrium has everything present in the same phase. The usual examples include reactions where everything is a gas, or everything is present in the same solution.

In writing an expression for equilibrium constant (Keq), we can start at a general case with the equation:[/cs_text][x_image type=”none” src=”https://easychem.com.au/wp-content/uploads/2019/06/homogeneous-equilibrium.jpg” alt=”” link=”false” href=”#” title=”” target=”” info=”none” info_place=”top” info_trigger=”hover” info_content=””][/cs_column][/cs_row][/cs_section][cs_section parallax=”false” separator_top_type=”none” separator_top_height=”50px” separator_top_angle_point=”50″ separator_bottom_type=”none” separator_bottom_height=”50px” separator_bottom_angle_point=”50″ style=”margin: 0px;padding: 45px 0px;”][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”][cs_text]Where A,B,C and D are the chemical species involved and a.b.c and d are the coefficients in the balanced chemical equation. According to the law of mass action, the equilibrium condition is described by the expression:[/cs_text][x_image type=”none” src=”https://easychem.com.au/wp-content/uploads/2019/06/equilibrium-condition.jpg” alt=”” link=”false” href=”#” title=”” target=”” info=”none” info_place=”top” info_trigger=”hover” info_content=””][/cs_column][/cs_row][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”][cs_text]If you allow this reaction to reach equilibrium and then measure the equilibrium concentrations of everything, you can combine these concentrations into an expression known as equilibrium constant.[/cs_text][/cs_column][/cs_row][cs_row inner_container=”true” marginless_columns=”false” style=”margin: 0px auto;padding: 0px;”][cs_column fade=”false” fade_animation=”in” fade_animation_offset=”45px” fade_duration=”750″ type=”1/1″ style=”padding: 0px;”] [/cs_column][/cs_row][/cs_section][/cs_content]

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